This NFPA Diamond 1-2-0 has the NFPA rating system for chemical safety and emergency response. A NFPA Diamond 1-2-0 is a helpful resource to aid in the protection of the health and safety of staff, and is not an alternative for required protective measures for eliminating or reducing hazards.
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NFPA 704 is the standard that is intended to provide a simple, readily recognized, and easily understood system of markings. These markings will provide a general idea of the hazards of a material and the severity of these hazards as they relate to emergency response.
In more specific terms the objectives of the system are to:
The system shall also enable fire-fighting, emergency, and other personnel to easily decide whether to evacuate the area or to commence emergency control procedures. It shall also assist those personnel in selecting fire-fighting tactics and emergency procedures.
Signs shall be in locations approved by the authority having jurisdiction and as a minimum shall be posted at the following locations:
This relates to the capability of a material to cause personal injury due to contact with or entry into the body via inhalation, skin contact, eye contact, or ingestion. All ratings are determined under emergency conditions.
Rating | Description |
|---|---|
 | Materials that can be lethal
|
 | Materials that can cause serious or permanent injury |
 | Materials that can cause temporary incapacitation or residual injury |
 | Materials that can cause significant irritation |
 | Materials that would offer no hazard beyond that of ordinary combustible material |
This relates to the degree of hazard due to reaction with ambient air, light, or both, and the degree of intrinsic susceptibility of materials to release energy by self-reaction or polymerization.
Rating | Description |
|---|---|
 | Materials that rapidly or completely vaporize at atmospheric pressure and
normal ambient temperature or that are readily dispersed in air and
burn readily |
 | Liquids and solids (including finely divided suspended solids)
that can be ignited under almost all ambient temperature conditions |
 | Materials that must be moderately heated or exposed to
relatively high ambient temperatures before ignition can occur |
 | Materials that must be preheated before ignition can occur |
 | Materials that will not burn under typical fire conditions |
This relates to the degree of hazard due to reaction with ambient air, light, or both, and the degree of intrinsic susceptibility of materials to release energy by self-reaction or polymerization.
Rating | Description |
|---|---|
 | Materials that can be lethal |
 | Materials that can cause serious or permanent injury |
 | Materials that can cause temporary incapacitation or residual injury |
 | Materials that can cause significant irritation |
 | Materials that would offer no hazard beyond that of ordinary combustible material |
This area of the diamond shall address water reactivity and oxidizing properties of the materials that cause special problems or require special fire-fighting techniques.
Rating | Description |
|---|---|
 | Material possesses oxidizing properties |
 | Material is a simple asphyxiant |
 | Material that reacts violently or explosively with water |
These special hazard symbols and others are not part of the NFPA 704 standard, but may be used if permitted by the authority having jurisdiction.
Rating | Description |
|---|---|
 | Material is an acid |
 | Material is a base (alkali)
|
 | Material is corrosive |
 | Material is cryogenic |
 | Material that is poisonous |
 | Material is radioactive |
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